Phytosterols (also called plant sterols) are a group of steroid alcohols, phytochemicals naturally occurring in plants. They are white powders with mild, characteristic odor, insoluble in water and soluble in alcohols. They have many applications as food additives, and in medicine and cosmetics.
- The molecule shown at the top of the page is β-sitosterol.
- By removing carbon 242, campesterol is obtained.
- By removing carbons 241 and 242, cholesterol is obtained.
- Removing a hydrogen from carbons 22 and 23 yields stigmasterol (stigmasta-5,22-dien-3β-ol).
- Removing carbon 242 and hydrogens from carbons 22 and 23 yields brassicasterol (ergosta-5,22-dien-3β-ol).
- Further removal of hydrogens from carbons 7 and 8 from brassicasterol yields ergosterol (ergosta-5,7,22-trien-3β-ol).
Plant structurePlants contain a range of phytosterols. They act as a structural component in the cell membrane, a role which in mammalian cells is played by cholesterol.
Detection of organic matterDue to its presence in terrestrial plant matter and only rare occurrence in unicellar algae, β-sitosterol can be used as a biomarker indicating the amount of terrestrially derived organic matter present in a sample. As these sterols are generally insoluble in water, they will partition onto suspended or settled solid matter (e.g. sediments). Due to grain surface area effects, muds will have greater concentrations by weight than sands or coarser grained sediments. To overcome this effect, ratios of individual sterols to total sterol content or cholesterol are usually used to indicate organic matter source.
Detection of adulterationPresence of brassicasterol, together with auxiliary markers α-linolenic acid and erucic acid, is a marker of adulteration of soybean oil and sunflower oil with rapeseed oil. As there is no brassicasterol in sunflower and soybean oil, but its concentration in rapeseed oil is about 1400 mg/kg, the amount of rapeseed oil added can be calculated. http://www.vupp.cz/envupp/falsificat.htm
Lowering cholesterolAs a food ingredient or additive, phytosterols have cholesterol-lowering properties (reducing cholesterol absorption in intestines), and may act in cancer prevention. Phytosterols occur naturally in small quantities in vegetable oils, especially sea buckthorn oil (1640mg/100g oil), corn oil (968mg/100g), and soybean oil (327mg/100g oil). One such phytosterol complex, isolated from vegetable oil, is cholestatin, composed of campesterol, stigmasterol, and brassicasterol, and is marketed as a dietary supplement. Sterols can reduce cholesterol in human subjects by up to 15%.
The mechanism behind phytosterols and the lowering of cholesterol occurs as follows: the incorporation of cholesterol into micelles in the gastrointestinal tract is inhibited, decreasing the overall amount of cholesterol absorbed. This may in turn help to control body total cholesterol levels, as well as modify HDL, LDL and TAG levels. Many margarines, butters, breakfast cereals and spreads are now enriched with phytosterols and marketed towards people wishing to lower their cholesterol levels.
phytosterol in German: Phytosterole
phytosterol in Spanish: Fitoesteroles
phytosterol in Indonesian: Fitosterol
phytosterol in Dutch: Plantensterolen
phytosterol in Japanese: フィトステロール
phytosterol in Romanian: Fitosterol
phytosterol in Russian: Фитостерол
phytosterol in Slovenian: Fitosterol
phytosterol in Finnish: Kasvisteroli
phytosterol in Turkish: Fitosterol